Pictet-Spengler reaction of biogenic amines with (2R)-N-glyoxyloylbornane-10,2-sultam.: Enantioselective synthesis of (S)-(+)-N-methylcalycotomine and (R)-(+)-xylopinine

被引：21

作者：

Czarnocki, Z ^{[1
]}

Arazny, Z ^{[1
]}

机构：

[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

HETEROCYCLES | 1999年 / 51卷 / 12期

关键词：

D O I：

10.3987/COM-99-8681

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Pictet-Spengler reaction of (2R)-N-glyoxyloylbornane-10,2-sultam with dopamine hydrochloride gave the condensation product, which was further converted into (S)-(+)-N)-methylcalycotomine and (R)-(+)-xylopinine of high enantiomeric purity.

引用

页码：2871 / 2879

页数：9

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