Compressing nearly hard sphere fluids increases glass fragility
被引:102
作者:
Berthier, L.
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Univ Montpellier 2, Lab Colloides Verres & Nanomat, UMR 5587, F-34095 Montpellier, France
CNRS, F-34095 Montpellier, FranceUniv Montpellier 2, Lab Colloides Verres & Nanomat, UMR 5587, F-34095 Montpellier, France
Berthier, L.
[1
,2
]
Witten, T. A.
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Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
Univ Chicago, Dept Phys, Chicago, IL 60637 USAUniv Montpellier 2, Lab Colloides Verres & Nanomat, UMR 5587, F-34095 Montpellier, France
Witten, T. A.
[3
,4
]
机构:
[1] Univ Montpellier 2, Lab Colloides Verres & Nanomat, UMR 5587, F-34095 Montpellier, France
[2] CNRS, F-34095 Montpellier, France
[3] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
[4] Univ Chicago, Dept Phys, Chicago, IL 60637 USA
We use molecular dynamics to investigate the glass transition occurring at large volume fraction,., and low temperature, T, in assemblies of soft repulsive particles. We find that equilibrium dynamics in the (phi, T)-plane obey a form of dynamic scaling in the proximity of a critical point at T = 0 and phi = phi(0), which should correspond to the ideal glass transition of hard spheres. This glass point, "point G", is distinct from athermal jamming thresholds. A remarkable consequence of scaling behaviour is that the dynamics at fixed phi passes smoothly from that of a strong glass to that of a very fragile glass as. increases beyond phi(0). Correlations between fragility and various physical properties are explored. Copyright (C) EPLA, 2009
机构:
Univ Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, FranceUniv Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, France
Sausset, Francois
Tarjus, Gilles
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Univ Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, FranceUniv Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, France
机构:
Univ Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, FranceUniv Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, France
Sausset, Francois
Tarjus, Gilles
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h-index: 0
机构:
Univ Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, FranceUniv Paris 06, CNRS, Lab Phys Theor Mat Condensee, UMR 7600, F-75252 Paris 05, France