Polymerisation of bis(trichlorophenolato)tri(pyridine)nickel and bis (trihalophenolato)di(pyridine)nickel (II) complexes in solid state

被引：14

作者：

Kisakürek, D ^{[1
]}

Aslan, A ^{[1
]}

Isçi, H ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

POLYMER | 2000年 / 41卷 / 14期

关键词：

bis(trihalophenolato)tri(pyridine)nickel(II); bis(trihalophenolato)di(pyridine)nickel(II); solid state thermal polymerisation;

D O I：

10.1016/S0032-3861(99)00749-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of five-coordinated bis(trihalophenolato)tri (pyridine)nickel (II) and four-coordinated his (trihalophenolato)di(pyridine) nickel(II) complexes from an aqueous solution and their characterisation by FT-IR, X-ray, DSC and elemental analysis is described. The thermal polymerisation of these complexes was carried out in the solid state and in the melt. Structural analyses were performed using H-1 NMRI C-13 NMR and FT-IR spectroscopic analyses. T(g)s were determined by differential thermal analysis and the molecular weights by viscometric method. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5149 / 5155

页数：7

共 24 条

[1]

ASLAN A, 1996, THESIS METU ANKARA

[2] SOLID-STATE POLYMERIZATION OF BIS(TRICHLOROPHENOXO) COBALT(II) COMPLEX TO GIVE POLY(DICHLOROPHENYLENE OXIDE) [J].

BASTURKMEN, M ;

ISCI, H ;

KISAKUREK, D .

POLYMER INTERNATIONAL, 1993, 30 (03) :387-392

[3] SYNTHESIS AND CHARACTERIZATION OF POLY(DICHLOROPHENYLENE OXIDE)S THROUGH SOLID-STATE THERMAL-DECOMPOSITION OF BIS(PYRIDINE)BIS(TRICHLOROPHENOXO)COPPER(II) COMPLEXES [J].

BASTURKMEN, M ;

KISAKUREK, D .

POLYMER, 1993, 34 (03) :625-629

[4]

BLANCHARD HS, 1962, J POLYM SCI, V58, P469, DOI 10.1002/pol.1962.1205816626

[5]

BOSCHKE FL, 1983, TABLES SPECTRAL DATA

[6] CHEMISTRY OF PHENOXO COMPLEXES .1. MECHANISM OF DECOMPOSITION OF PHENOXOCOPPER(II) COMPLEXES [J].

CARR, B ;

HARROD, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (17) :5707-5712

[7] CHEMISTRY OF PHENOXO COMPLEXES .2. SYNTHESIS OF HIGH MOLECULAR-WEIGHT POLY(2,6-DICHLOROPHENYLENE OXIDES) [J].

CARR, BG ;

HARROD, JF ;

VANGHELU.P .

MACROMOLECULES, 1973, 6 (04) :498-502

[8] FURTHER-STUDIES OF THE STRUCTURE OF POLY(DIHALOPHENYLENE OXIDES) USING CARBON NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

HARROD, JF ;

VANGHELUWE, P ;

KISAKUREK, D ;

SHAVER, A .

MACROMOLECULES, 1981, 14 (03) :565-570

[9]

HARROD JF, 1982, MACROMOLECULES, V95, P676

[10] A catalytic decomposition of certain phenol silver salts - [First paper] [J].

Hunter, WH ;

Olson, AO ;

Daniels, EA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1916, 38 :1761-1771

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