Connecting local structure to interface formation: A molecular scale van der Waals theory of nonuniform liquids

被引：100

作者：

Weeks, JD ^{[1
]}

机构：

[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA

[2] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY | 2002年 / 53卷

关键词：

molecular field theory; Gaussian fluctuations; wetting and drying transitions; linear response theory; hydrophobic interactions;

D O I：

10.1146/annurev.physchem.53.100201.133929

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article reviews a new and general theory of nonuniform fluids that naturally incorporates molecular scale information into the classical van der Waals theory of slowly varying interfaces. The method optimally combines two standard approximations, molecular (mean) field theory to describe interface formation and linear response (or Gaussian fluctuation) theory to describe local structure. Accurate results have been found in many different applications in nonuniform simple fluids and these ideas may have important implications for the theory of hydrophobic interactions in water.

引用

页码：533 / 562

页数：30

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