Daphnezomines L, M, N, and O, new alkaloids from Daphniphyllum humile

被引：39

作者：

Morita, H ^{[1
]}

Kobayashi, J ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON | 2002年 / 58卷 / 33期

关键词：

alkaloids; imine; conformation; NMR;

D O I：

10.1016/S0040-4020(02)00737-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Four new alkaloids, daphnezomines L-O (1-4), have been isolated from the stems of Daphniphyllum humile, and the structures and the relative stereochemistry were elucidated on the basis of spectroscopic data. The structure of daphnezomine L (1) was close to that of a biogenetic intermediate from secodaphnane to daphnane skeletons proposed previously. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6637 / 6641

页数：5

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