Water adsorption in MOFs: fundamentals and applications

被引：1109

作者：

Canivet, Jerome ^{[1
]}

Fateeva, Alexandra ^{[2
]}

Guo, Youmin ^{[1
]}

Coasne, Benoit ^{[3
,4
]}

Farrusseng, David ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, UMR 5256, IRCELYON, F-69626 Villeurbanne, France

[2] Univ Lyon 1, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France

[3] MIT, CNRS, UMI 3466, Cambridge, MA 02139 USA

[4] MIT, Dept Civil & Environm Engn, Cambridge, MA 02139 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2014年 / 43卷 / 16期

关键词：

METAL-ORGANIC FRAMEWORKS; MICROPOROUS COORDINATION POLYMERS; HIGH PROTON CONDUCTIVITY; HEAT TRANSFORMATION; THERMAL-STABILITY; STRUCTURAL TRANSITIONS; HYDROGEN ADSORPTION; FUNCTIONAL-GROUPS; CO2; ADSORPTION; POROUS SILICA;

D O I：

10.1039/c4cs00078a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review article presents the fundamental and practical aspects of water adsorption in Metal-Organic Frameworks (MOFs). The state of the art of MOF stability in water, a crucial issue to many applications in which MOFs are promising candidates, is discussed here. Stability in both gaseous (such as humid gases) and aqueous media is considered. By considering a non-exhaustive yet representative set of MOFs, the different mechanisms of water adsorption in this class of materials are presented: reversible and continuous pore filling, irreversible and discontinuous pore filling through capillary condensation, and irreversibility arising from the flexibility and possible structural modifications of the host material. Water adsorption properties of more than 60 MOF samples are reported. The applications of MOFs as materials for heat-pumps and adsorbent-based chillers and proton conductors are also reviewed. Some directions for future work are suggested as concluding remarks.

引用

页码：5594 / 5617

页数：24

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