Perfluoropentacene: High-performance p-n junctions and complementary circuits with pentacene

被引:679
作者
Sakamoto, Y
Suzuki, T [1 ]
Kobayashi, M
Gao, Y
Fukai, Y
Inoue, Y
Sato, F
Tokito, S
机构
[1] Inst Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Kanto Denka Kogyo Co Ltd, New Prod Dev Div, Chiyoda Ku, Tokyo 1000005, Japan
[3] NHK Japan Broadcasting Corp, Setagaya Ku, Tokyo 1578510, Japan
关键词
D O I
10.1021/ja0476258
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis and characterization of perfluoropentacene as an n-type semiconductor for organic field-effect transistors (OFETs). Perfluoropentacene is a planar and crystalline material that adopts a herringbone structure as observed for pentacene. OFETs with perfluoropentacene were constructed using top-contact geometry, and an electron mobility of 0.11 cm2 V-1 s-1 was observed. Bipolar OFETs with perfluoropentacene and pentacene function at both negative and positive gate voltages. The improved p-n junctions are probably due to the similar d-spacings of both acenes. Complementary inverter circuits were fabricated, and the transfer characteristics exhibit a sharp inversion of the output signal with a high-voltage gain. Copyright © 2004 American Chemical Society.
引用
收藏
页码:8138 / 8140
页数:3
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