Acrylic-based resin with favorable properties for three-dimensional two-photon polymerization

被引：158

作者：

Baldacchini, T

LaFratta, CN

Farrer, RA

Teich, MC

Saleh, BEA

Naughton, MJ

Fourkas, JT ^{[1
]}

机构：

[1] Boston Coll, Eugene F Merkert Chem Ctr, Chestnut Hill, MA 02467 USA

[2] Boston Univ, Dept Elect & Comp Engn, Quantum Imaging Lab, Boston, MA 02215 USA

[3] Boston Coll, Dept Phys, Chestnut Hill, MA 02467 USA

来源：

JOURNAL OF APPLIED PHYSICS | 2004年 / 95卷 / 11期

关键词：

D O I：

10.1063/1.1728296

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We describe an acrylic-based prepolymer resin that is ideally suited for the fabrication of three-dimensional structures with two-photon polymerization. We characterize the photochemical and photophysical properties of the photoinitiator and present representative structures that demonstrate the favorable mechanical and optical properties of the polymer. (C) 2004 American Institute of Physics.

引用

收藏

页码：6072 / 6076

页数：5

相关论文

共 19 条

[1] Efficient multiphoton polymerization for the fabrication of 3-dimensional microstructures [J].

Baldacchini, T ;

Farrer, RA ;

Moser, J ;

Fourkas, JT ;

Naughton, MJ .

SYNTHETIC METALS, 2003, 135 (1-3) :11-12

[2] Multiphoton photopolymerization with a Ti:sapphire oscillator [J].

Baldacchini, T ;

Chen, H ;

Farrer, RA ;

Previte, MJR ;

Moser, J ;

Naughton, MJ ;

Fourkas, JT .

COMMERCIAL AND BIOMEDICAL APPLICATIONS OF ULTRAFAST AND FREE-ELECTRON LASERS, 2002, 4633 :136-144

[3] Near-IR two-photon photoinitiated polymerization using a fluorone/amine initiating system [J].

Belfield, KD ;

Ren, XB ;

Van Stryland, EW ;

Hagan, DJ ;

Dubikovsky, V ;

Miesak, EJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (06) :1217-1218

[4] Two-photon-induced fluorescence [J].

Callis, PR .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1997, 48 (01) :271-297

[5] 3-dimensional submicron polymerization of acrylamide by multiphoton excitation of xanthene dyes [J].

Campagnola, PJ ;

Delguidice, DM ;

Epling, GA ;

Hoffacker, KD ;

Howell, AR ;

Pitts, JD ;

Goodman, SL .

MACROMOLECULES, 2000, 33 (05) :1511-1513

[6] Probing the reactivity of photoinitiators for free radical polymerization: Time-resolved infrared spectroscopic study of benzoyl radicals [J].

Colley, CS ;

Grills, DC ;

Besley, NA ;

Jockusch, S ;

Matousek, P ;

Parker, AW ;

Towrie, M ;

Turro, NJ ;

Gill, PMW ;

George, MW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (50) :14952-14958

[7] Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication [J].

Cumpston, BH ;

Ananthavel, SP ;

Barlow, S ;

Dyer, DL ;

Ehrlich, JE ;

Erskine, LL ;

Heikal, AA ;

Kuebler, SM ;

Lee, IYS ;

McCord-Maughon, D ;

Qin, JQ ;

Röckel, H ;

Rumi, M ;

Wu, XL ;

Marder, SR ;

Perry, JW .

NATURE, 1999, 398 (6722) :51-54

[8] 2-PHOTON LASER SCANNING FLUORESCENCE MICROSCOPY [J].

DENK, W ;

STRICKLER, JH ;

WEBB, WW .

SCIENCE, 1990, 248 (4951) :73-76

[9] Finer features for functional microdevices - Micromachines can be created with higher resolution using two-photon absorption. [J].

Kawata, S ;

Sun, HB ;

Tanaka, T ;

Takada, K .

NATURE, 2001, 412 (6848) :697-698

[10] Three-dimensional microfabrication with two-photon-absorbed photopolymerization [J].

Maruo, S ;

Nakamura, O ;

Kawata, S .

OPTICS LETTERS, 1997, 22 (02) :132-134