Tandem isomerization/Claisen transformation of allyl homoallyl and diallyl ethers into γ,δ-unsaturated aldehydes with a new three component catalyst Ru3(CO)12/imidazolinium salt/Cs2CO3

被引：33

作者：

Le Nôtre, J ^{[1
]}

Brissieux, L ^{[1
]}

Sémeril, D ^{[1
]}

Bruneau, C ^{[1
]}

Dixneuf, PH ^{[1
]}

机构：

[1] Univ Rennes, CNRS, UMR 6509, Inst Chim, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 16期

关键词：

D O I：

10.1039/b205805g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The three component catalyst Ru-3(CO)(12)/1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride/Cs2CO3 (molar ratio 1 3: 6) successively promotes both allyl to vinyl isomerization and Claisen rearrangement from allyl homoallyl and diallyl ethers to selectively afford gamma,delta-unsaturated aldehydes.

引用

页码：1772 / 1773

页数：2

共 24 条

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