Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology

被引：179

作者：

Sonnauer, Andreas ^{[1
]}

Hoffmann, Frank ^{[2
]}

Froeba, Michael ^{[2
]}

Kienle, Lorenz ^{[3
]}

Duppel, Viola ^{[3
]}

Thommes, Matthias ^{[4
]}

Serre, Christian ^{[5
]}

Ferey, Gerard ^{[5
]}

Stock, Norbert ^{[1
]}

机构：

[1] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany

[2] Univ Hamburg, Inst Inorgan & Appl Chem, D-20146 Hamburg, Germany

[3] Univ Kiel, Inst Mat Sci, D-24143 Kiel, Germany

[4] Quantachrome Instruments, Boynton Beach, FL 33426 USA

[5] Univ Versailles St Quentin, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 21期

关键词：

high-throughput methods; mesoporous materials; metal-organic frameworks; solvothermal synthesis; structure simulation; METAL-ORGANIC-FRAMEWORKS; POSTSYNTHETIC COVALENT MODIFICATION; ZEOLITIC IMIDAZOLATE FRAMEWORKS; HIGH-THROUGHPUT SYNTHESIS; COORDINATION-POLYMER; HYBRID COMPOUNDS; DRUG-DELIVERY; TEMPERATURE; ADSORPTION; CATALYSIS;

D O I：

10.1002/anie.200805980

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large, larger,... Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 Å. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N2-sorption, and TEM investigations. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3791 / 3794

页数：4

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