The synthesis of epi-epoxydon utilising the Baylis-Hillman reaction

被引：26

作者：

Genski, T ^{[1
]}

Taylor, RJK ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(02)00529-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

-(+/-)-epi-Epoxydon was synthesised by means of a triethylaluminium/ tri-n-butylphosphine-catalysed Baylis-Hillman reaction between an O-protected epoxidised hydroxyquinol core and paraformaldehyde, constituting the first application of the Baylis-Hillman reaction to a highly functionalised beta-substituted enone. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3573 / 3576

页数：4

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