Germanium telluride nanowires and nanohelices with memory-switching behavior

被引:112
作者
Yu, Dong [1 ]
Wu, Junqiao [1 ]
Gu, Qian [1 ]
Park, Hongkun [1 ]
机构
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
D O I
10.1021/ja0625071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis of single-crystalline GeTe nanowires (NWs) and nanohelices (NHs) using a vapor transport method assisted by metal catalysts. The NWs have typical diameters of 65 ± 20 nm and lengths reaching up to 50 μm, while NHs have an average helix diameter of 135 ± 30 nm, with widely varying pitches. Electron microscopy and diffraction measurements show that these NWs and NHs are single crystalline and exhibit a rhombohedral structure. The devices incorporating individual GeTe NWs exhibit nonvolatile resistance changes associated with voltage-driven crystalline-amorphous transitions, suggesting that these NWs can be the basis of an electrically driven nonvolatile memory. Copyright © 2006 American Chemical Society.
引用
收藏
页码:8148 / 8149
页数:2
相关论文
共 26 条
[11]   Superconducting NbSe2 nanowires and nanoribbons converted from NbSe3 nanostructures -: art. no. 142506 [J].
Hor, YS ;
Welp, U ;
Ito, Y ;
Xiao, ZL ;
Patel, U ;
Mitchell, JF ;
Kwok, WK ;
Crabtree, GW .
APPLIED PHYSICS LETTERS, 2005, 87 (14) :1-3
[12]   Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes [J].
Hu, JT ;
Odom, TW ;
Lieber, CM .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (05) :435-445
[13]  
Huang MH, 2001, ADV MATER, V13, P113, DOI 10.1002/1521-4095(200101)13:2<113::AID-ADMA113>3.0.CO
[14]  
2-H
[15]   Single-crystal nanorings formed by epitaxial self-coiling of polar nanobelts [J].
Kong, XY ;
Ding, Y ;
Yang, R ;
Wang, ZL .
SCIENCE, 2004, 303 (5662) :1348-1351
[16]   Low-cost and nanoscale non-volatile memory concept for future silicon chips [J].
Lankhorst, MHR ;
Ketelaars, BWSMM ;
Wolters, RAM .
NATURE MATERIALS, 2005, 4 (04) :347-352
[17]   Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies [J].
Murray, CB ;
Kagan, CR ;
Bawendi, MG .
ANNUAL REVIEW OF MATERIALS SCIENCE, 2000, 30 :545-610
[18]   REVERSIBLE ELECTRICAL SWITCHING PHENOMENA IN DISORDERED STRUCTURES [J].
OVSHINSKY, SR .
PHYSICAL REVIEW LETTERS, 1968, 21 (20) :1450-+
[19]  
Patzke GR, 2002, ANGEW CHEM INT EDIT, V41, P2446, DOI 10.1002/1521-3773(20020715)41:14<2446::AID-ANIE2446>3.0.CO
[20]  
2-K