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Uranium-sulfilimine chemistry.: Hydrolysis Cp*2UCl2 with HNSPh2 • H2O and the crystal structure of CP*2UCl(OH)(HNSPh2), a metallocene terminal hydroxy complex of tetravalent uranium

被引：17
作者：
Ariyaratne, KANS [1 ]
Cramer, RE
Jameson, GB
Gilje, JW
机构：
[1] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand
[2] Univ Hawaii Manoa, Dept Chem, Honolulu, HI 96822 USA
[3] James Madison Univ, Dept Chem, Harrisonburg, VA 22807 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 11期
基金：
美国国家科学基金会;
关键词：
f-element; actinide; uranium; hydroxide; metallocene;
D O I：
10.1016/j.jorganchem.2004.03.029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Cp*2UCl2(HNSPh2) with HNSPh2 (.) H2O in 1: 1 stoichiometry, produces Cp*2UC(OH)(HNSPh2) in good yield. This is the first structurally characterized metallocene f-element complex containing a terminal hydroxy ligand. Cp*2UCl(OH)(HNSPh2) is an intermediate in the formation of a tetra uranium-oxo-cluster [Cp*(Cl)(HNSPh2)U(mu(3)-O)(mu(2)-O)U(Cl)(HNSPh2)(2)](2), which forms by hydrolysis of Cp*2UCl2 with excess HNSPh2 (.) H2O. (C) 2004 Elsevier B.V. All rights reserved.
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收藏
页码：2029 / 2032
页数：4
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