Synthesis of tunable phosphinite-pyridine ligands and their applications in asymmetric hydrogenation

被引：37

作者：

Liu, Qi-Bin ^{[1
]}

Yu, Chang-Bin ^{[1
]}

Zhou, Yong-Gui ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 27期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tetlet.2006.04.111

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new class of modular conformationally rigid N,P ligands is conveniently synthesized from readily available starting material. Iridium complexes with these ligands have demonstrated excellent enantioselectivity (Lip to 99% ee) in the asymmetric hydrogenation of aryl alkenes. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4733 / 4736

页数：4

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