Heterogeneous suzuki reactions catalyzed by Pd(0)-Y zeolite

被引:105
作者
Artok, L [1 ]
Bulut, H [1 ]
机构
[1] Izmir Inst Technol, Fac Sci, Dept Chem, TR-35430 Izmir, Turkey
关键词
suzuki reaction; coupling; palladium; zeolite; heterogeneous; catalysts; aryl halides;
D O I
10.1016/j.tetlet.2004.03.126
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Pd(0)-Y zeolite showed high activity in the Suzuki cross-coupling reactions of aryl bromides without added ligands. The type of base and organic solvent were found to be critical for the efficiency of the reaction. The presence of water was essential within the reaction medium. The coupling reactions occurred on the external surface of the zeolite. The catalyst is reusable. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3881 / 3884
页数:4
相关论文
共 39 条
  • [1] Akiyama R, 2001, ANGEW CHEM INT EDIT, V40, P3469, DOI 10.1002/1521-3773(20010917)40:18<3469::AID-ANIE3469>3.0.CO
  • [2] 2-T
  • [3] A mild and versatile method for palladium-catalyzed cross-coupling of aryl halides in water and surfactants
    Arcadi, A
    Cerichelli, G
    Chiarini, M
    Correa, M
    Zorzan, D
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (20) : 4080 - 4086
  • [4] An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water
    Baleizao, C
    Corma, A
    García, H
    Leyva, A
    [J]. CHEMICAL COMMUNICATIONS, 2003, (05) : 606 - 607
  • [5] Palladium-catalyzed C-C coupling under thermomorphic conditions
    Bergbreiter, DE
    Osburn, PL
    Wilson, A
    Sink, EM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) : 9058 - 9064
  • [6] Suzuki cross-coupling reactions of aryl halides with arylboronic acids catalysed by Pd(II)-NaY zeolite
    Bulut, H
    Artok, L
    Yilmaz, S
    [J]. TETRAHEDRON LETTERS, 2003, 44 (02) : 289 - 291
  • [7] Bifunctional palladium-basic zeolites as catalyst for Suzuki reaction
    Corma, A
    García, H
    Leyva, A
    [J]. APPLIED CATALYSIS A-GENERAL, 2002, 236 (1-2) : 179 - 185
  • [8] Pd-zeolites as heterogeneous catalysts in Heck chemistry
    Dams, M
    Drijkoningen, L
    Pauwels, B
    Van Tendeloo, G
    De Vos, DE
    Jacobs, PA
    [J]. JOURNAL OF CATALYSIS, 2002, 209 (01) : 225 - 236
  • [9] Heterogeneously catalysed Heck reaction using palladium modified zeolites
    Djakovitch, L
    Koehler, K
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 142 (02) : 275 - 284
  • [10] Heck reactions between aryl halides and olefins catalysed by Pd-complexes entrapped into zeolites NaY
    Djakovitch, L
    Heise, W
    Köhler, K
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 584 (01) : 16 - 26