Enantioselective total synthesis of (-)-xialenon A

被引：10

作者：

Hodgson, DM ^{[1
]}

Galano, JM ^{[1
]}

Christlieb, M ^{[1
]}

机构：

[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 20期

关键词：

D O I：

10.1039/b208485f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first total synthesis of (-)-xialenon A (1) via conjugate allylation of a 1,5-cyclooctadiene-derived bicyclo[3.3.0]octenone 3 and an alpha'-hydroxylation on the more hinderd face of enone 9 using hypervalent iodine chemistry, is described.

引用

页码：2436 / 2437

页数：2

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