Synthesis of 1,3-disubstituted naphthalenes from the Baylis-Hillman acetates with the aid of manganese(III) acetate

被引：62

作者：

Im, YJ

Lee, KY

Kim, TH

Kim, JN ^{[1
]}

机构：

[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea

[2] Chonnam Natl Univ, Inst Basic Sci, Kwangju 500757, South Korea

[3] Chonnam Natl Univ, Fac Appl Chem, Kwangju 500757, South Korea

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 26期

关键词：

Baylis-Hillman acetate; naphthalene; manganese(III) acetate; malonyl radical;

D O I：

10.1016/S0040-4039(02)00884-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3-Disubstituted naphthalene derivatives can be easily synthesized from Baylis-Hillman acetates by successive reaction: (1) S(N)2' type reaction with diethyl malonate or ethyl nitroacetate; (2) manganese(III) acetate-assisted radical cyclization and (3) aromatization with NaI/O-2 system or elimination of nitrous acid. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4675 / 4678

页数：4

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