An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes

被引：1435

作者：

Li, Nian-Wu ^{[1
,2
]}

Yin, Ya-Xia ^{[1
,2
]}

Yang, Chun-Peng ^{[1
,2
,3
]}

Guo, Yu-Guo ^{[1
,2
,3
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

ADVANCED MATERIALS | 2016年 / 28卷 / 09期

基金：

中国国家自然科学基金;

关键词：

RAY PHOTOELECTRON-SPECTROSCOPY; LIQUID ELECTROLYTES; ELECTROCHEMISTRY; DEPOSITION; CONDUCTOR; GROWTH; LI;

D O I：

10.1002/adma.201504526

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Li3PO4 solid electrolyte interphase (SEI) layer is demonstrated to be stable in the organic electrolyte, even during the Li deposition/dissolution process. Thus, the Li-conducting Li3PO4 SEI layer with a high Young's modulus can effectively reduce side reactions between Li metal and the electrolyte and can restrain Li dendrite growth in lithium-metal batteries during cycling. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：1853 / 1858

页数：6

相关论文

共 41 条

[1] Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries [J].

Aurbach, D .

JOURNAL OF POWER SOURCES, 2000, 89 (02) :206-218

[2] A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].

Aurbach, D ;

Zinigrad, E ;

Cohen, Y ;

Teller, H .

SOLID STATE IONICS, 2002, 148 (3-4) :405-416

[3]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]

[4] Functional Materials for Rechargeable Batteries [J].

Cheng, Fangyi ;

Liang, Jing ;

Tao, Zhanliang ;

Chen, Jun .

ADVANCED MATERIALS, 2011, 23 (15) :1695-1715

[5] Dendrite-Free Nanostructured Anode: Entrapment of Lithium in a 3D Fibrous Matrix for Ultra-Stable Lithium-Sulfur Batteries [J].

Cheng, Xin-Bing ;

Peng, Hong-Jie ;

Huang, Jia-Qi ;

Wei, Fei ;

Zhang, Qiang .

SMALL, 2014, 10 (21) :4257-4263

[6] Micromorphological studies of lithium electrodes in alkyl carbonate solutions using in situ atomic force microscopy [J].

Cohen, YS ;

Cohen, Y ;

Aurbach, D .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (51) :12282-12291

[7] X-Ray Photoelectron Spectroscopy Investigations of Carbon-Coated LixFePO4 Materials [J].

Dedryvere, R. ;

Maccario, M. ;

Croguennec, L. ;

Le Cras, F. ;

Delmas, C. ;

Gonbeau, D. .

CHEMISTRY OF MATERIALS, 2008, 20 (22) :7164-7170

[8] Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode [J].

Ding, Fei ;

Xu, Wu ;

Chen, Xilin ;

Zhang, Jian ;

Engelhard, Mark H. ;

Zhang, Yaohui ;

Johnson, Bradley R. ;

Crum, Jarrod V. ;

Blake, Thomas A. ;

Liu, Xingjiang ;

Zhang, Ji-Guang .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (10) :A1894-A1901

[9] Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism [J].

Ding, Fei ;

Xu, Wu ;

Graff, Gordon L. ;

Zhang, Jian ;

Sushko, Maria L. ;

Chen, Xilin ;

Shao, Yuyan ;

Engelhard, Mark H. ;

Nie, Zimin ;

Xiao, Jie ;

Liu, Xingjiang ;

Sushko, Peter V. ;

Liu, Jun ;

Zhang, Ji-Guang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (11) :4450-4456

[10]

Harry KJ, 2014, NAT MATER, V13, P69, DOI [10.1038/NMAT3793, 10.1038/nmat3793]

← 1 2 3 4 5 →