Developments of lithium-ion batteries and challenges of LiFePO4 as one promising cathode material

被引：182

作者：

Li, Zhihua ^{[1
]}

Zhang, Duanming ^{[1
]}

Yang, Fengxia ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Phys, Wuhan 430074, Peoples R China

来源：

JOURNAL OF MATERIALS SCIENCE | 2009年 / 44卷 / 10期

基金：

美国国家科学基金会;

关键词：

PULSED-LASER DEPOSITION; CARBON-COATED LIFEPO4; SOLID-STATE SYNTHESIS; ELECTROCHEMICAL PROPERTIES; THIN-FILMS; HYDROTHERMAL SYNTHESIS; SECONDARY BATTERIES; ELECTRODE MATERIAL; PHOSPHO-OLIVINES; ROOM-TEMPERATURE;

D O I：

10.1007/s10853-009-3316-z

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Developments and developing trends of lithium-ion batteries (LIBs) are summarized first: it is proposed that solid thin film microbatteries and large-scale all-solid-state rechargeable LIBs are the two main developing tendencies. Meanwhile, cost and safety issues are the primary limitations to improve advanced LIBs with excellent electrochemical performance. Next, one of the most promising cathode materials, LiFePO4, is introduced in detail. Advantages and drawbacks of LiFePO4 as cathode active material are analyzed, then, main approaches to circumvent its drawbacks proposed by many groups are also summarized. In addition, some mechanism investigations on this cathode material presently and challenging problems waiting for solutions before LiFePO4 can be commercialized are also discussed in this review.

引用

页码：2435 / 2443

页数：9

共 91 条

[1] Structural and magnetic properties of LiFePO4 and lithium extraction effects [J].

Ait-Salah, A. ;

Dodd, J. ;

Mauger, A. ;

Yazami, R. ;

Gendron, F. ;

Julien, C. M. .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (8-9) :1598-1605

[2] Magnetic studies of the carbothermal effect on LiFePO4 [J].

Ait-Salah, A ;

Zaghib, K ;

Mauger, A ;

Gendron, F ;

Julien, CM .

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2006, 203 (01) :R1-R3

[3] Ionic and electronic transport in single crystalline LiFePO4 grown by optical floating zone technique [J].

Amin, R. ;

Maier, J. ;

Balaya, P. ;

Chen, D. P. ;

Lin, C. T. .

SOLID STATE IONICS, 2008, 179 (27-32) :1683-1687

[4] Development of a high power lithium secondary battery for hybrid electric vehicles [J].

Arai, J ;

Yamaki, T ;

Yamauchi, S ;

Yuasa, T ;

Maeshima, T ;

Sakai, T ;

Koseki, M ;

Horiba, T .

JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :788-792

[5] Cycle life evaluation of 3 Ah LixMn2O4-based lithium-ion secondary cells for low-earth-orbit satellites II. Harvested electrode examination [J].

Brown, Shelley ;

Ogawa, Keita ;

Kumeuchi, Youichi ;

Enomoto, Shinsuke ;

Uno, Masatoshi ;

Saito, Hirobumi ;

Sone, Yoshitsugu ;

Abraham, Daniel ;

Lindbergh, Goran .

JOURNAL OF POWER SOURCES, 2008, 185 (02) :1454-1464

[6] Kinetic study on low-temperature synthesis of LiFePO4 via solid-state reaction [J].

Chang, Hao-Hsun ;

Chang, Chun-Chih ;

Wu, Hung-Chun ;

Guo, Zheng-Zhao ;

Yang, Mo-Hua ;

Chiang, Yung-Ping ;

Sheu, Hwo-Shuenn ;

Wu, Nae-Lih .

JOURNAL OF POWER SOURCES, 2006, 158 (01) :550-556

[7] The hydrothermal synthesis and characterization of olivines and related compounds for electrochemical applications [J].

Chen, Jiajun ;

Vacchio, Michael J. ;

Wang, Shijun ;

Chernova, Natalya ;

Zavalij, Peter Y. ;

Whittingham, M. Stanley .

SOLID STATE IONICS, 2008, 178 (31-32) :1676-1693

[8] Hydrothermal synthesis of lithium iron phosphate [J].

Chen, Jiajun ;

Whittingham, M. Stanley .

ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (05) :855-858

[9] Electronically conductive phospho-olivines as lithium storage electrodes [J].

Chung, SY ;

Bloking, JT ;

Chiang, YM .

NATURE MATERIALS, 2002, 1 (02) :123-128

[10] Recent developments in Li-ion prismatic cells [J].

Cousseau, Jean-Francois ;

Siret, Clemence ;

Biensan, Philippe ;

Broussely, Michel .

JOURNAL OF POWER SOURCES, 2006, 162 (02) :790-796

← 1 2 3 4 5 6 7 8 9 10 →