Palladium Nanoparticle Incorporation in Conjugated Microporous Polymers by Supercritical Fluid Processing

被引：123

作者：

Hasell, Tom

Wood, Colin D.

Clowes, Rob

Jones, James T. A.

Khimyak, Yaroslav Z.

Adams, Dave J.

Cooper, Andrew I. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMISTRY OF MATERIALS | 2010年 / 22卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

CATALYZED COUPLING REACTIONS; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; RECYCLABLE CATALYSTS; CARBON-DIOXIDE; SURFACE-AREA; SPILLOVER; CHEMISTRY; POLYSTYRENE; PLATINUM;

D O I：

10.1021/cm9030446

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium nanoparticles have been dispersed uniformly throughout it microporous poly(aryleneethynylene) material by the infusion of a CO2-soluble Id precursor. The resulting composite has good thermal stability and has potential applications for example in heterogeneous catalysis. The porosity of the polymeric Support Was maintained after inclusion of the metal and the hydrogen Uptake at room temperature Was increased with respect to the unloaded porous Support.

引用

收藏

页码：557 / 564

页数：8

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