Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs

被引：646

作者：

Moemming, Cornelia M. ^{[1
]}

Otten, Edwin ^{[2
]}

Kehr, Gerald ^{[1
]}

Froehlich, Roland ^{[1
]}

Grimme, Stefan ^{[1
]}

Stephan, Douglas W. ^{[2
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 36期

基金：

加拿大自然科学与工程研究理事会;

关键词：

boranes; carbon dioxide fixation; frustrated Lewis pairs; phosphines; HETEROLYTIC DIHYDROGEN ACTIVATION; FREE CATALYTIC-HYDROGENATION; N-HETEROCYCLIC CARBENES; ZETA-VALENCE QUALITY; GAUSSIAN-BASIS SETS; CO2; BORANE; CHEMISTRY; IMINES; ACID;

D O I：

10.1002/anie.200901636

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hot and bothered? Frustrated Lewis pairs comprising phosphine and borane react to reversibly bind and release CO2, offering a rare example of metal-free CO2 sequestration. The mechanism of formation of these CO2 derivatives 1 and 2 (see scheme) by almost simultaneous P - C and O - B bond formation was characterized by quantum chemical calculations. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：6643 / 6646

页数：4

共 80 条

[1]

[Anonymous], 1995, ANGEW CHEM

[2]

[Anonymous], 1995, Angew. Chem., DOI DOI 10.1002/ANGE.19951072005

[3]

[Anonymous], 2008, ANGEW CHEM

[4]

[Anonymous], 2009, ANGEW CHEM, DOI DOI 10.1002/ANGE.200901399

[5] Isolation and structural determination of two derivatives of the elusive carbamic acid [J].

Aresta, M ;

Ballivet-Tkatchenko, D ;

Dell'Amico, DB ;

Bonnet, MC ;

Boschi, D ;

Calderazzo, F ;

Faure, RE ;

Labella, L ;

Marchetti, F .

CHEMICAL COMMUNICATIONS, 2000, (13) :1099-1100

[6] Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].

Aresta, Michele ;

Dibenedetto, Angela .

DALTON TRANSACTIONS, 2007, (28) :2975-2992

[7] Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems [J].

Axenov, Kirill V. ;

Kehr, Gerald ;

Froehlich, Roland ;

Erker, Gerhard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (10) :3454-+

[8] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[9] Zwitterionic 18-electron d0-anionic metallocene complexes [J].

Cadierno, V ;

Zablocka, M ;

Donnadieu, B ;

Igau, A ;

Majoral, JP .

ORGANOMETALLICS, 1999, 18 (10) :1882-1886

[10] PHOSPHORANES .6. DETERMINATION OF GROUND-STATE STRUCTURES OF TRIFLUOROMETHYLPHOSPHORANES BY MEANS OF C-13 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY - CORRELATION OF 1JPC WITH TRIGONAL-BIPYRAMIDAL SITE AND RELATION BETWEEN 1JPC AND 2JPF OF CF3 SUBSTITUENTS IN PHOSPHORANES [J].

CAVELL, RG ;

GIBSON, JA ;

THE, KI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (24) :7841-7847

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