Electrochemically induced fluorinative ring expansion of cycloalkylideneacetates

被引：29

作者：

Hara, S

Chen, SQ

Hoshio, T

Fukuhara, T

Yoneda, N

机构：

[1] Div. of Molec. Chemistry, Graduate School of Engineering, Hokkaido University

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 47期

关键词：

D O I：

10.1016/0040-4039(96)01953-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical oxidation of cyclic unsaturated esters (1) was carried out using Et(3)N-5HF as the electrolyte. The ring expansion and fluorination took place to give beta,beta-difluorocycloalkanecarboxylic esters (2) selectively. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：8511 / 8514

页数：4

共 5 条

[1] CHEN SQ, 1996, IN PRESS ELECTROCHIM
[2] ELECTROCHEMICAL FLUORINATIVE ALPHA-CLEAVAGE OF CYCLIC-KETONES - SYNTHESIS OF FLUOROCARBOXYLIC ACID-ESTERS
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CHEN, SQ
HATAKEYAMA, T
FUKUHARA, T
SEKIGUCHI, M
YONEDA, N
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[3] OXIDATIVE FLUORINATION IN AMINE-HF MIXTURES
MEURS, JHH
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[4] WOVKULICH PM, 1991, COMPREHENSIVE ORGANI, V1, P843
[5] SELECTIVE ELECTROCHEMICAL FORMYL HYDROGEN-EXCHANGE FLUORINATION OF ALIPHATIC-ALDEHYDES TO PREPARE ACYL FLUORIDES USING HF-BASE SOLUTIONS
YONEDA, N
CHEN, SQ
HATAKEYAMA, T
HARA, S
FUKUHARA, T
[J]. CHEMISTRY LETTERS, 1994, (05) : 849 - 850

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