Highly porous PProDOT-Et2 film as counter electrode for plastic dye-sensitized solar cells

被引：87

作者：

Lee, Kun-Mu ^{[2
]}

Hsu, Chih-Yu ^{[1
]}

Chen, Po-Yen ^{[1
]}

Ikegami, Masashi ^{[3
]}

Miyasaka, Tsutomu ^{[3
]}

Ho, Kuo-Chuan ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

[2] Ind Technol Res Inst, Photovolta Technol Ctr, Chutunghsinchu 31040, Taiwan

[3] Toin Univ Yokohama, Grad Sch Engn, Kanagawa 2258502, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2009年 / 11卷 / 18期

关键词：

MESOSCOPIC TITANIA; PERFORMANCE; BEHAVIOR;

D O I：

10.1039/b823011k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A poly(3,3-diethyl-3,4-dihydro-2H-thieno-[3,4-b][1,4]dioxepine) (PProDOT-Et-2) counter electrode was incorporated in a plastic dye-sensitized solar cell (DSSC) to substitute for Pt electrode. The surface morphology and I-/I-3(-) redox behaviors based on PProDOT-Et-2 and sputtered-Pt electrodes were characterized, and their performances as counter electrodes in the plastic-DSSCs were compared. Cells fabricated with a PProDOT-Et-2 counter electrode showed a higher conversion efficiency of 5.20% compared with cell fabricated with sputtered-Pt (5.11%) electrodes under the illumination of 100 mW cm(-2). This enhancement was attributed to the increase in the effective surface area and good catalytic properties of PProDOT-Et-2 for

引用

页码：3375 / 3379

页数：5

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