Caveats for poly(methimazolyl) borate chemistry:: the novel inorganic heterocycles[H2C(mt)2BR2] Cl (mt = methimazolyl; BR2 = BH2, BH(mt), 9-BBN)

被引：25

作者：

Crossley, IR ^{[1
]}

Hill, AF ^{[1
]}

Humphrey, ER ^{[1
]}

Smith, MK ^{[1
]}

Tshabang, N ^{[1
]}

Willis, AC ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 16期

关键词：

D O I：

10.1039/b407733d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Whilst frequently used for reactions of poly(methimazolyl) borates, dichloromethane is not an innocent solvent, but rather slowly forms heterocyclic salts [H2C(mt)(2)BR2] Cl, three examples of which (BR2=BH2, BH(mt), 9-borabicyclononyl) have been structurally characterised to confirm the unprecedented B(NCS)(2)C connectivity.

引用

页码：1878 / 1879

页数：2

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