Hydrogen storage in a highly porous solid derived from γ-zirconium phosphate

被引:41
作者
Brunet, Ernesto [1 ]
Alhendawi, Hussein M. H.
Cerro, Carlos
de la Mata, Maria Jose
Juanes, Olga
Rodriguez-Ubis, Juan Carlos
机构
[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
[2] Univ Autonoma Madrid, Fac Ciencias C1, SIdI, E-28049 Madrid, Spain
关键词
hydrogen storage; organic-inorganic hybrid composites; porous materials; zirconium;
D O I
10.1002/anie.200602445
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Having a gas: Topotactic exchange (65 %) of γ-zirconium phosphate with terphenyl-diphosphonic acid yielded a pillared material with a specific area of 90 m2g-1. Subsequent treatment with hypophosphorous acid afforded a material of α type, with no incorporated hypophosphite and a specific area of 400 m2g-1, which took up 74 cm3g-1 of H2 at 650 Torr and 77 K. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6918 / 6920
页数:3
相关论文
共 13 条
[1]   Engineering of microcrystaline solid-state networks using cross-linked γ-zirconium phosphate/hypophosphite with nonrigid polyethylenoxadiphosphonates.: Easy access to porously dynamic solids with polar/nonpolar pores [J].
Brunet, E ;
de la Mata, MJ ;
Alhendawi, HMH ;
Cerro, C ;
Alonso, M ;
Juanes, O ;
Rodríguez-Ubis, JC .
CHEMISTRY OF MATERIALS, 2005, 17 (06) :1424-1433
[2]   Solid-state reshaping of crystals:: Flash increase in porosity of zirconium phosphate-hypophosphite that contains polyethylenoxa diphosphonate pillars [J].
Brunet, E ;
de la Mata, MJ ;
Juanes, O ;
Rodríguez-Ubis, JC .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (05) :619-621
[3]  
BRUNET E, 2004, ANGEW CHEM, V116, P629
[4]   Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].
Chen, BL ;
Eddaoudi, M ;
Hyde, ST ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2001, 291 (5506) :1021-1023
[5]   Organically pillared microporous zirconium phosphonates [J].
Clearfield, A ;
Wang, ZK .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (15) :2937-2947
[6]   Hydrogen adsorption in nanoporous Nickel(II) phosphates [J].
Forster, PM ;
Eckert, J ;
Chang, JS ;
Park, SE ;
Férey, G ;
Cheetham, AK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (05) :1309-1312
[7]   The hydrogen solution [J].
Kennedy, D .
SCIENCE, 2004, 305 (5686) :917-917
[8]   Light metal hydrides and complex hydrides for hydrogen storage [J].
Schüth, F ;
Bogdanovic, B ;
Felderhoff, M .
CHEMICAL COMMUNICATIONS, 2004, (20) :2249-2258
[9]  
TAMOU Y, 2005, MATERIA, V44, P188
[10]   Sulfonated microporous organic-inorganic hybrids as strong bronsted acids [J].
Wang, ZK ;
Heising, JM ;
Clearfield, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10375-10383