Organic ultraviolet photovoltaic diodes based on copper phthalocyanine as an electron acceptor

被引:31
作者
Chen, L. L.
Li, W. L. [1 ]
Wei, H. Z.
Chu, B.
Li, B.
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited States Proc, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] NE Normal Univ, Fac Chem, Inst Funct Mat Chem, Changchun 130024, Peoples R China
关键词
organic; ultraviolet; photovoltaic diodes; copper phthalocyanine;
D O I
10.1016/j.solmat.2005.11.005
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Organic ultraviolet (UV) light-sensitive photovoltaic (PV) diodes, based on 4, 4', 4"-tris(2-methylphenyl phenylamino) triphenylamine (m-MTDATA) as an electron donor and copper phthalocyanine (CuPc) as acceptor, have been fabricated. The PV diode exhibits high open-circuit voltage (V-OC) of 1.05 V under illumination of 365 nm UV light with 1.7 mW/cm(2), although the CuPc was generally used as electron donor in other PV diodes. And the short-circuit current (I-SC) of 54.6 mu A/cm(2), fill factor (FF) of 0.304 and power conversion efficiency (eta(e)) of 1.03% are respectively achieved. This diode can accurately detect the UV radiation according to photo-generated voltage signal. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1788 / 1796
页数:9
相关论文
共 21 条
[1]   Organic field-effect transistors with high mobility based on copper phthalocyanine [J].
Bao, Z ;
Lovinger, AJ ;
Dodabalapur, A .
APPLIED PHYSICS LETTERS, 1996, 69 (20) :3066-3068
[2]   Temperature dependence.of the.performance of ultraviolet detectors [J].
Blank, TV ;
Goldberg, YA ;
Konstantinov, OV .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2003, 509 (1-3) :109-117
[3]   Influence of molecular architecture and intermixing on the photovoltaic, morphological and spectroscopic properties of CuPc-C60 heterojunctions [J].
Heutz, S ;
Sullivan, P ;
Sanderson, BM ;
Schultes, SM ;
Jones, TS .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 83 (2-3) :229-245
[4]   Metal-dependent charge transfer and chemical interaction at interfaces between 3,4,9,10-perylenetetracarboxylic bisimidazole and gold, silver and magnesium [J].
Hill, I. G. ;
Schwartz, J. ;
Kahn, A. .
ORGANIC ELECTRONICS, 2000, 1 (01) :5-13
[5]   Voltage reduction in organic light-emitting diodes [J].
Hung, LS ;
Mason, MG .
APPLIED PHYSICS LETTERS, 2001, 78 (23) :3732-3734
[6]   Influence of temperature and drive current on degradation mechanisms in organic light-emitting diodes [J].
Ishii, M ;
Taga, Y .
APPLIED PHYSICS LETTERS, 2002, 80 (18) :3430-3432
[7]   Exciplex formation at the organic solid-state interface: Yellow emission in organic light-emitting diodes using green-fluorescent tris(8-quinolinolato)aluminum and hole-transporting molecular materials with low ionization potentials [J].
Itano, K ;
Ogawa, H ;
Shirota, Y .
APPLIED PHYSICS LETTERS, 1998, 72 (06) :636-638
[8]   ELECTRON AND HOLE MOBILITY IN TRIS(8-HYDROXYQUINALINOLATO-N1,O8) ALUMINUM [J].
KEPLER, RG ;
BEESON, PM ;
JACOBS, SJ ;
ANDERSON, RA ;
SINCLAIR, MB ;
VALENCIA, VS ;
CAHILL, PA .
APPLIED PHYSICS LETTERS, 1995, 66 (26) :3618-3620
[9]   Ultraviolet-ray irradiation and degradation evaluation of the sealing agent EVA film for solar cells under high temperature and humidity [J].
Kojima, T ;
Yanagisawa, T .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 85 (01) :63-72
[10]   High contrast ratio organic light-emitting devices based on CuPC as electron transport material [J].
Lee, JH ;
Liao, CC ;
Hu, PJ ;
Chang, Y .
SYNTHETIC METALS, 2004, 144 (03) :279-283