Gold catalysis:: No steric limitations in the phenol synthesis

被引：91

作者：

Hashmi, A. Stephen K. ^{[1
]}

Salathe, Ralph ^{[1
]}

Frey, Wolfgang ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 26期

关键词：

cyclization; dihydroisoindoles; gold; homogeneous catalysis; tetrahydroisoquinolines;

D O I：

10.1002/chem.200600533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Different dihydroisoindol-4-ols and 8-hydroxytetrahydroisoquinolines were prepared by the gold-catalyzed phenol synthesis. The reaction was investigated with several sterically demanding groups in the 5-position of the furan starting material. The influence of the reaction time and the catalyst on the yield was investigated.

引用

页码：6991 / 6996

页数：6

共 35 条

[31] Intramolecular Diels-Alder reaction of dinitro-olefin derivatives of furan for the preparation of a versatile tool: 3,7-dinitro-11-oxatricycloundec-9-ene [J].

Sader-Bakaouni, L ;

Charton, O ;

Kunesch, N ;

Tillequin, F .

TETRAHEDRON, 1998, 54 (09) :1773-1782

[32] UNUSUAL CATIONIC SINGLE-BRIDGED BINUCLEAR COMPLEXES OF GOLD(I) AND GOLD(III) [J].

USON, R ;

LAGUNA, A ;

CASTRILLO, MV .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1979, 9 (04) :317-324

[33] The effect of halogen phosphor on alkyl formanilide - A new method for the characterisation of secondary and tertiary p-alkylamino-benzaldehyde [J].

Vilsmeier, A ;

Haack, A .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1927, 60 :119-122

[34]

*WIL VCH, 1999, ORGANIKUM, P422

[35] Development of the Pictet-Spengler reaction catalyzed by AuCl3/AgOTf [J].

Youn, SW .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (06) :2521-2523

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