Novel Knoevenagel-type reaction via titanium enolate derived from Ti(O-i-Pr)4 and diketene

被引：14

作者：

Hayashi, M ^{[1
]}

Nakamura, N ^{[1
]}

Yamashita, K ^{[1
]}

机构：

[1] Kobe Univ, Dept Chem, Fac Sci, Kobe, Hyogo 6578501, Japan

来源：

TETRAHEDRON | 2004年 / 60卷 / 32期

关键词：

knoevenagel reaction; titanium enolate; diketene;

D O I：

10.1016/j.tet.2004.06.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Knoevenagel-type reaction between diketene and aldehydes proceeded in the presence of Ti(O-i-Pr)(4). This reaction proceeded via titanium enolate derived from Ti(O-i-Pr)(4) and diketene. As for the stereoselectivity of the products, E-isomers were produced predominantly in the case of aromatic aldehydes. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：6777 / 6783

页数：7

共 13 条

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