Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) - Transition metal complexes and related catalytic, medicinal and photoluminescent applications

被引：392

作者：

Phillips, AD

Gonsalvi, L

Rornerosa, A

Vizza, F

Peruzzini, M

机构：

[1] CNR, Ist Chim COmposti Organomet, ICCOM, Area Ric Firenze, I-50019 Florence, Italy

[2] Univ Almeria, Fac Ciencias Expt, Area Quim Inorgan, Almeria 04071, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 11-12期

关键词：

1,3,5-triaza-7-phosphaadamantane; water-soluble ligands; phosphines; homogeneous catalysis; medicinal chemistry; luminescence;

D O I：

10.1016/j.ccr.2004.03.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cage-like water-soluble monodentate phosphine 1,3,5-triaza-7-phosphaadamantane (PTA) has received renewed interest in the recent literature due to its properties to solubilize transition metal complexes in aqueous phase. This property has allowed application of Rh, Ru and Pd-PTA complexes in aqueous phase or biphasic homogeneous catalysis, antitumoral tests (Ru- and Pt-PTA) and photoluminescence (Au-PTA). This paper reviews the synthesis and structural properties of PTA and derivatives, their transition metal complexes, catalytic, medicinal and photoluminescence uses. (C) 2004 Elsevier B.V. All rights reserved.

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页码：955 / 993

页数：39

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