Secondary building units, nets and bonding in the chemistry of metal-organic frameworks

被引：2198

作者：

Tranchemontagne, David J. ^{[1
]}

Mendoza-Cortes, Jose L. ^{[1
]}

O'Keeffe, Michael ^{[1
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Ctr Reticular Chem, Los Angeles, CA 90095 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 05期

关键词：

N; N-DIALKYLCARBAMATO LANTHANIDE COMPLEXES; BASIC CARBOXYLATE COMPOUNDS; SINGLE-MOLECULE MAGNETS; RAY CRYSTAL-STRUCTURES; X-RAY; STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; TRANSITION-METALS; CLUSTER COMPOUNDS; LUMINESCENCE PROPERTIES;

D O I：

10.1039/b817735j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This critical review presents a comprehensive study of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal-organic frameworks (MOFs). We describe the geometries of 131 SBUs, their connectivity and composition. This contribution presents a comprehensive list of the wide variety of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) in the construction and synthesis of metal-organic frameworks. The SBUs discussed here were obtained from a search of molecules and extended structures archived in the Cambridge Structure Database (CSD, version 5.28, January 2007) which included only crystals containing metal carboxylate linkages (241 references).

引用

页码：1257 / 1283

页数：27

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