A new facile synthesis of tertiary dithioesters

被引:26
作者
Alberti, A
Benaglia, M
Laus, M
Sparnacci, K
机构
[1] CNR, ISOF, Ist Sintesi Organ & Fotoreattiv, Area Ricerca, I-40129 Bologna, Italy
[2] INSTM, Dipartimento Sci & Tecnol Avanzate, UdR Alessandria, I-15100 Alessandria, Italy
关键词
D O I
10.1021/jo026162q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Thermal decomposition of tertiary azo compounds in the presence of a triphenylmethyl dithioester results in the formation of the corresponding tertiary dithioesters. This procedure is especially useful for the synthesis of tertiary phosphoryldithioformates, but also represents an easy synthetic methodology of general applicability.
引用
收藏
页码:7911 / 7914
页数:4
相关论文
共 20 条
[1]   Phosphoryldithioformates: Part V. Unusual linewidth variations in the ESR spectra of some spin adducts of (dimenthoxy)phosphoryl methyl dithioformate [J].
Alberti, A ;
Benaglia, M ;
Macciantelli, D ;
Hudson, A ;
Masson, S .
MAGNETIC RESONANCE IN CHEMISTRY, 2002, 40 (06) :387-390
[2]   Phosphoryldithioformates as spin trapping agents and process stabilizers - 3 [J].
Alberti, A ;
Benaglia, M ;
Bonora, M ;
Borzatta, V ;
Hudson, A ;
Macciantelli, D ;
Masson, S .
POLYMER DEGRADATION AND STABILITY, 1998, 62 (03) :559-567
[3]   EPR studies on phosphoryldithioformates .2. [J].
Alberti, A ;
Benaglia, M ;
DellaBona, MA ;
Macciantelli, D ;
Heuze, B ;
Masson, S ;
Hudson, A .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (06) :1057-1063
[4]   Phosphoryl- and thiophosphoryl-dithioformates. Part IV. Electrochemical reduction and EPR study of the radical anions [J].
Alberti, A ;
Benaglia, M ;
Hapiot, P ;
Hudson, A ;
Le Coustumer, G ;
Macciantelli, D ;
Masson, S .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (09) :1908-1913
[5]   Kinetic investigations of reversible addition fragmentation chain transfer polymerizations: Cumyl phenyldithioacetate mediated homopolymerizations of styrene and methyl methacrylate [J].
Barner-Kowollik, C ;
Quinn, JF ;
Nguyen, TLU ;
Heuts, JPA ;
Davis, TP .
MACROMOLECULES, 2001, 34 (22) :7849-7857
[6]   A new practical synthesis of tertiary S-alkyl dithiocarbonates and related derivatives [J].
Bouhadir, G ;
Legrand, N ;
Quiclet-Sire, B ;
Zard, SZ .
TETRAHEDRON LETTERS, 1999, 40 (02) :277-280
[7]   Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].
Chiefari, J ;
Chong, YK ;
Ercole, F ;
Krstina, J ;
Jeffery, J ;
Le, TPT ;
Mayadunne, RTA ;
Meijs, GF ;
Moad, CL ;
Moad, G ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 1998, 31 (16) :5559-5562
[8]  
DUUS F, 1979, COMPREHENSIVE ORGANI
[9]  
LAUS M, 2001, MACROMOLECULES, V34, P7629
[10]  
Le T. P., 1998, [No title captured], Patent No. [WO9801478A1, 9801478, WO 98/01478]