Nanoscale depth-resolved cathodoluminescence spectroscopy of ZnO surfaces and metal interfaces

被引:14
作者
Brillson, L. J. [1 ,2 ,3 ]
Mosbacker, H. L. [2 ]
Doutt, D. L. [2 ]
Dong, Y. [3 ]
Fang, Z. -Q. [4 ,5 ]
Look, D. C. [4 ,5 ]
Cantwell, G. [6 ]
Zhang, J. [6 ]
Song, J. J. [6 ]
机构
[1] Ohio State Univ, Dept Elect & Comp Engn, Columbus, OH 43210 USA
[2] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA
[3] Ohio State Univ, Ctr Mat Res, Columbus, OH 43210 USA
[4] Wright State Univ, Semicond Res Ctr, Dayton, OH 45433 USA
[5] USAF, Mat & Mfg Directorate, Res Lab, Wright Patterson AFB, OH 45433 USA
[6] ZN Technol Inc, Brea, CA 92821 USA
基金
美国国家科学基金会;
关键词
Cathodoluminescence spectroscopy; ZnO; Defects; Surface; Interface; Scanning electron microscope; Atomic force microscopy; Kelvin probe force microscopy; ATOMIC DIFFUSION; DEFECTS; MORPHOLOGY; STATES;
D O I
10.1016/j.spmi.2008.11.008
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The electronic properties of ZnO surfaces and interfaces has until recently been relatively unexplored. We have used a complement of ultrahigh vacuum scanning electron microscope (SEM)-based, depth-resolved cathodoluminescence spectroscopy (DRCLS), temperature-dependent charge transport, trap spectroscopy, and surface science techniques to probe the electronic and chemical properties of clean surfaces and interfaces on a nanometer scale. DRCLS reveals remarkable nanoscale correlations of native point defect distributions with surface and sub-surface defects calibrated with capacitance trap spectroscopies, atomic force microscopy, and Kelvin probe force microscopy. The measurement of these near-surface states associated with native point defects in the ZnO bulk and those induced by interface chemical bonding is a powerful extension of cathodoluminescence spectroscopy that provides a guide to understanding and controlling ZnO electronic contacts. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:206 / 213
页数:8
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