Multifluorination toward High-Mobility Ambipolar and Unipolar n-Type Donor-Acceptor Conjugated Polymers Based on Isoindigo

被引：191

作者：

Gao, Yao ^{[1
,2
]}

Deng, Yunfeng ^{[3
,4
]}

Tian, Hongkun ^{[1
]}

Zhang, Jidong ^{[1
]}

Yan, Donghang ^{[1
]}

Geng, Yanhou ^{[1
,3
,4
,5
]}

Wang, Fosong ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China

[4] Tianjin Univ, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300072, Peoples R China

[5] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 13期

基金：

中国国家自然科学基金;

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; STRUCTURE-PROPERTY RELATIONSHIPS; HETEROJUNCTION SOLAR-CELLS; DIRECT ARYLATION POLYCONDENSATION; HIGH-ELECTRON-MOBILITY; HIGH-PERFORMANCE; SIDE-CHAINS; SEMICONDUCTING POLYMERS; BACKBONE FLUORINATION;

D O I：

10.1002/adma.201606217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using a "multifluorination" strategy, ambipolar donor-acceptor conjugated polymer with hole and electron mobility (mu(h) and mu(e)) up to 3.94 and 3.50 cm(2) V-1 s(-1), respectively, and unipolar n-type donor-acceptor conjugated polymers with mu(e) up to 4.97 cm(2) V-1 s(-1) is synthesized with isoindigo as acceptor units.

引用

页数：7

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