Electrografting of 3-methyl thiophene onto carbon fiber:: characterizatioi and carbazole random copolymer by FTIR-ATR, SEM, EDX

被引：39

作者：

Saraç, AS ^{[1
]}

Springer, J ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Tech Chem, Fachgebiet Makromol Chem, D-10623 Berlin, Germany

来源：

SURFACE & COATINGS TECHNOLOGY | 2002年 / 160卷 / 2-3期

关键词：

electrografting; carbon fiber; electrocopolymerization; carbazole; 3-methylthiophene; scanning electron microscopy;

D O I：

10.1016/S0257-8972(02)00388-2

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Electrografting of poly(3-methylthiophene-co-carbazole) onto high tenacity (TENAX HTA 5000) carbon fiber was carried out under preparative constant-current electrolysis conditions by electropolymerizing in non-aqueous media. The surface morphology of the electrografted carbon fibers was determined by scanning electron microscopy (SEM). For characterization of the chemical composition of the random copolymer, FTIR reflectance measurements (FTIR-ATR) were performed. The efficiency of the electrocopolymerization on carbon fiber surfaces under preparative constant-current electrolysis conditions as a function of the experimental conditions was evaluated (effect on thickness and morphology). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：227 / 238

页数：12

共 30 条

[1] Poly(carbazole-co-acrylamide) electrocoated carbon fibers and their adhesion behavior to an epoxy resin matrix [J].

Bismarck, A ;

Menner, A ;

Kumru, ME ;

Saraç, AS ;

Bistritz, M ;

Schulz, E .

JOURNAL OF MATERIALS SCIENCE, 2002, 37 (03) :461-471

[2] Electrografting of poly (carbazole-co-acrylamide) onto highly oriented pyrolytic graphite.: A cyclovoltammetric, atomic force microscopic and ellipsometric study [J].

Bismarck, A ;

Menner, A ;

Barner, J ;

Lee, AF ;

Wilson, K ;

Springer, J ;

Rabe, JP ;

Saraç, AS .

SURFACE & COATINGS TECHNOLOGY, 2001, 145 (1-3) :164-175

[3] A new poly(3-alkylthiophene) synthesis via Pd-catalyzed coupling of thienyl mercuric chlorides [J].

Curtis, MD ;

McClain, MD .

CHEMISTRY OF MATERIALS, 1996, 8 (04) :936-944

[4] Poly{arylene-alt-[bis(1-methylpyrrolylene)]}s .1. Synthesis and electrochemical polymerization of terarenes [J].

Geissler, U ;

Hallensleben, ML ;

Rohde, N .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (08) :2565-2576

[5] Electrically conductive copolymers based on 1-methylpyrrole [J].

Geissler, U ;

Hallensleben, ML ;

Rohde, N .

SYNTHETIC METALS, 1997, 84 (1-3) :173-174

[6] FLEXIBLE LIGHT-EMITTING-DIODES MADE FROM SOLUBLE CONDUCTING POLYMERS [J].

GUSTAFSSON, G ;

CAO, Y ;

TREACY, GM ;

KLAVETTER, F ;

COLANERI, N ;

HEEGER, AJ .

NATURE, 1992, 357 (6378) :477-479

[7] SYNTHESIS AND PROPERTIES OF POLY(3,4-DIMETHOXYTHIOPHENE) [J].

HAGIWARA, T ;

YAMAURA, M ;

SATO, K ;

HIRASAKA, M ;

IWATA, K .

SYNTHETIC METALS, 1989, 32 (03) :367-379

[8]

HARISINGH N, 1997, HDB ORGANIC CONDUCTI

[9] AN INTERPRETATION OF THE VIBRATIONAL-SPECTRA OF INSULATING AND ELECTRICALLY CONDUCTING POLY(3-METHYLTHIOPHENE) AIDED BY A THEORETICAL DYNAMICAL MODEL [J].

HERNANDEZ, V ;

RAMIREZ, FJ ;

OTERO, TF ;

NAVARRETE, JTL .

JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (01) :114-129

[10] INFRARED DICHROIC STUDIES OF POLYTHIOPHENES [J].

HOTTA, S ;

SOGA, M ;

SONODA, N .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (12) :4994-4998

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