Effect of sodium and oxygen doping on the conductivity of CuInS2 thin films

被引:9
作者
Scheer, R
Luck, I
Kanis, M
Kurps, R
Krüger, D
机构
[1] Hahn Meitner Inst Kernforsch Berlin GmbH, D-14109 Berlin, Germany
[2] Inst Halbleitertphys, D-15230 Frankfurt, Germany
关键词
chalcopyrite; CuInS2; doping; oxidation; conductivity;
D O I
10.1016/S0040-6090(99)00843-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Doping of Cu-poor CuInS2 thin films by sodium and oxygen species, such as O-2 and O, was investigated by SIMS and conductivity measurements. Increased oxygen concentration is found for Na-doping. The SIMS signals of CuO and CuOS were detected. They coincide for O-doped films but differ for Na and O-2 doped films. This is interpreted as due to grain boundary effects. Na doping lends to an increase in lateral conductivity. This finding supports the model previously proposed by [L. Kronik, D. Cahen, H.W. Schock, Adv. Mater. 10(1998)31] that oxygen plays a major role in Na doping. The presented results. furthermore, propose oxygen single doping for chalcopyrite films. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:468 / 472
页数:5
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