Cobalt-substituted SnO2 thin films:: A transparent ferromagnetic semiconductor

被引:44
作者
Gopinadhan, K. [1 ]
Pandya, Dinesh K. [1 ]
Kashyap, Subhash C. [1 ]
Chaudhary, Sujeet [1 ]
机构
[1] Indian Inst Technol, Dept Phys, Thin Film Lab, New Delhi 110016, India
关键词
D O I
10.1063/1.2204328
中图分类号
O59 [应用物理学];
学科分类号
摘要
A maximum room temperature ferromagnetic moment of 0.47 mu(B)/Co ion has been observed in Sn0.9Co0.1O2-delta films grown by spray pyrolysis. The films have high conductivity (similar to 150 Omega(-1) cm(-1)) and similar to 70% transmittance in the visible region. A systematic variation of saturation magnetization, carrier concentration, electrical conductivity, and optical transmission edge in Sn1-xCoxO2-delta (0.05 <= x <= 0.15) films is correlated with the change in Co concentration, and a carrier mediated Ruderman-Kittel-Kasuya-Yoshida interaction has been proposed as the most probable mechanism for the ferromagnetic ordering. The maximum blueshift in the transmission edge by similar to 215 meV (at x=0.10) is attributed to the extra carriers generated by Co substitution. (c) 2006 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 18 条
[1]   On the room-temperature ferromagnetism in (ZnO)0.98(MnO2)0.02 [J].
Bhatti, KP ;
Chaudhary, S ;
Pandya, DK ;
Kashyap, SC .
SOLID STATE COMMUNICATIONS, 2005, 136 (07) :384-388
[2]   Ferromagnetism in (In, Mn)As alloy thin films [J].
Blattner, AJ ;
Wessels, BW .
APPLIED SURFACE SCIENCE, 2004, 221 (1-4) :155-159
[3]   TRANSPARENT CONDUCTORS - A STATUS REVIEW [J].
CHOPRA, KL ;
MAJOR, S ;
PANDYA, DK .
THIN SOLID FILMS, 1983, 102 (01) :1-46
[4]   Free carrier-induced ferromagnetism in structures of diluted magnetic semiconductors [J].
Dietl, T ;
Haury, A ;
dAubigne, YM .
PHYSICAL REVIEW B, 1997, 55 (06) :R3347-R3350
[5]   SnO2 doped with Mn, Fe or Co:: Room temperature dilute magnetic semiconductors [J].
Fitzgerald, CB ;
Venkatesan, M ;
Douvalis, AP ;
Huber, S ;
Coey, JMD ;
Bakas, T .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (11) :7390-7392
[6]   Cobalt-doped ZnO - a room temperature dilute magnetic semiconductor [J].
Fitzgerald, CB ;
Venkatesan, M ;
Lunney, JG ;
Dorneles, LS ;
Coey, JMD .
APPLIED SURFACE SCIENCE, 2005, 247 (1-4) :493-496
[7]   Intrinsic ferromagnetism in insulating cobalt doped anatase TiO2 -: art. no. 157204 [J].
Griffin, KA ;
Pakhomov, AB ;
Wang, CM ;
Heald, SM ;
Krishnan, KM .
PHYSICAL REVIEW LETTERS, 2005, 94 (15)
[8]   Relationship between the structural and magnetic properties of Co-doped SnO2 nanoparticles -: art. no. 075203 [J].
Hays, J ;
Punnoose, A ;
Baldner, R ;
Engelhard, MH ;
Peloquin, J ;
Reddy, KM .
PHYSICAL REVIEW B, 2005, 72 (07)
[9]   Origins of coexistence of conductivity and transparency in SnO2 -: art. no. 095501 [J].
Kiliç, Ç ;
Zunger, A .
PHYSICAL REVIEW LETTERS, 2002, 88 (09) :955011-955014
[10]   High temperature ferromagnetism with a giant magnetic moment in transparent Co-doped SnO2-δ -: art. no. 077205 [J].
Ogale, SB ;
Choudhary, RJ ;
Buban, JP ;
Lofland, SE ;
Shinde, SR ;
Kale, SN ;
Kulkarni, VN ;
Higgins, J ;
Lanci, C ;
Simpson, JR ;
Browning, ND ;
Das Sarma, S ;
Drew, HD ;
Greene, RL ;
Venkatesan, T .
PHYSICAL REVIEW LETTERS, 2003, 91 (07)