Investigation of an Anode Catalyst for a Direct Dimethyl Ether Fuel Cell

被引:21
作者
Cai, Ke-Di [1 ]
Yin, Ge-Ping [1 ]
Wang, Jia-Jun [1 ]
Lu, Lei-Lei [1 ]
机构
[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China
关键词
MULTIWALLED CARBON NANOTUBES; PLATINUM; ELECTROCATALYSTS; ELECTROOXIDATION; PERFORMANCE; NANOPARTICLES; DEPOSITION; MECHANISM; SUPPORT; BLACKS;
D O I
10.1021/ef8005965
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this work, we compared investigation of Pt/multiwalled carbon nanotubes (MWNTs) and Pt/Vulcan XC-72 anode catalysts for direct dimethyl ether fuel cells (DDFC). The homemade catalysts were characterized using a transmission electron micrograph (TEM) and X-ray diffraction (XRD). The cyclic voltammogram analyses revealed that the Pt/MWNTs showed a higher catalytic activity for dimethyl ether electro-oxidation, compared with the Pt/Vulcan XC-72 catalyst. The membrane electrode assembly (MEA) with the Pt/MWNTs anode catalyst presented the maximum power density of 38.4 mW cm(-2), which was higher than that with the Pt/Vulcan XC-72 one (32.4 mW cm(-2)). Moreover, the performance decay rate of the MEA with Pt/MWNTs was lower than that with Pt/Vulcan XC-72 (after a 56 h test). It indicated that the Pt/MWNTs can be expected to be a more suitable catalyst for the DDFC.
引用
收藏
页码:903 / 907
页数:5
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