Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation

被引:164
作者
Jerphagnon, T [1 ]
Renaud, JL [1 ]
Bruneau, C [1 ]
机构
[1] Univ Rennes 1, UMR 6509, Inst Chim, F-35042 Rennes, France
关键词
D O I
10.1016/j.tetasy.2004.04.037
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review reports the recent developments in the field of asymmetric hydrogenation in the presence of metal catalysts containing monodentate phosphorus ligands. Besides monophosphines, that have been used at the origin of asymmetric hydrogenation, it mainly includes the use of monophosphites and monophosphoramidites, which when associated to rhodium precursors have recently led to very efficient enantioselective catalytic systems. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2101 / 2111
页数:11
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