Bonded cellulose-derived high-performance liquid chromatography chiral stationary phases .2. Influence of the porosity of the silica gel matrix on performance

被引:32
作者
Minguillon, C
Franco, P
Oliveros, L
机构
[1] UNIV BARCELONA,FAC FARM,QUIM FARMACEUT LAB,E-08028 BARCELONA,SPAIN
[2] CONSERVATOIRE NATL ARTS & METIERS,LAB CHIM GEN,F-75141 PARIS 03,FRANCE
关键词
chiral stationary phases; LC; cellulose stationary phases; enantiomer separation;
D O I
10.1016/0021-9673(95)01203-6
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Two cellulose derivatives bearing simultaneously 10-undecenoyl and 3,5-dimethylphenylaminocarbonyl groups in different ratios were chemically bonded on allylsilica gels of different porosity. The systematic study of the effect of the silica gel pore size on the bonding of the polysaccharide derivative and on the performance of the resulting chiral supports is presented.
引用
收藏
页码:415 / 422
页数:8
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