Use of real-time ion-mass spectrometry and discharge voltage trending for analysis of a-Si DC plasma CVD processes

被引:4
作者
Ganguly, G [1 ]
Newton, J [1 ]
Carlson, DE [1 ]
Arya, RR [1 ]
机构
[1] BP Solar, N Amer Technol Ctr, Toano, VA 23168 USA
关键词
D O I
10.1016/S0022-3093(02)00935-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
DC discharge voltage monitoring is a convenient non-intrusive tool for in-line monitoring of plasma-deposited amorphous silicon deposition processes. We discuss the observed variations of the discharge voltage due to (i) changing hydrogen dilution of silane, (ii) etch back of silicon by a hydrogen plasma, (iii) admixing of germane and methane and correlate the results with in situ ion-mass spectroscopy, We suggest that negative ion formation by electron attachment to silane and/or higher-silane species causes the changes of discharge voltage. Time dependences following discharge initiation are discussed in terms of the relative concentrations of silane versus higher-silane species. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:53 / 57
页数:5
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