Interstrand interactions between side chains in a double-helical foldamer

被引:98
作者
Haldar, Debasish
Jiang, Hua
Leger, Jean-Michel
Huc, Ivan
机构
[1] Inst European Chim & Biol, F-33607 Pessac, France
[2] Lab Pharmacochim, F-33076 Bordeaux, France
关键词
helical structures; molecular recognition; supramolecular chemistry;
D O I
10.1002/anie.200600698
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Hairy molecules! The numerous benzyloxy side chains sticking out of a helically folded pyridine carboxamide oligomer bring about considerable stabilization to its double-helical conformation. The structure of the duplex was studied both in solution and in the solid state. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5483 / 5486
页数:4
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