EPR and 1H NMR spectroscopic study of the CrIII(salen) Cl catalysts

被引:17
作者
Bryliakov, KP [1 ]
Lobanova, MV [1 ]
Talsi, EP [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 11期
关键词
D O I
10.1039/b203369k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An EPR and H-1, H-2 NMR study of the Cr-III (salen) Cl type complexes was performed for the first time; the X-band EPR spectra of the S=3/2 Cr-III (salen) Cl complexes were interpreted using analytical expressions to reveal the g-factors and fine structure parameters, and assignment of the H-1 and H-2 NMR resonances was made.
引用
收藏
页码:2263 / 2265
页数:3
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