Porphyrin based metallamacrocycles

被引：24

作者：

Deiters, Emmanuel ^{[1
]}

Bulach, Veronique ^{[1
]}

Hosseini, Mir Wais ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7140, Chim Coordinat Organ Lab, F-67000 Strasbourg, France

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 09期

关键词：

D O I：

10.1039/b606041m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon combining 5,10-dipyridyl-15,20-diphenylporphyrin 1 or its copper metallated complex 2 with metal halides (MX2: M = Zn, Cd, Hg; X = I or Br) five [2 + 2] metallamacrocycles of the square type were obtained and structurally characterised in the crystalline phase by X-ray diffraction methods. Whereas the free porphyrin 1 leads to the formation of homobinuclear metallamacrocycles with both CdI2 and HgI2, a homotetranuclear metallamacrocycle resulting from the metallation of the porphyrin core is obtained in the presence of ZnI2. When using the premetallated copper complex 2, two heterotetranuclear metallamacrocycles are generated in the presence of CdI2 and HgBr2.

引用

页码：1289 / 1294

页数：6

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