Rhodium-catalyzed asymmetric arylative ring opening of bicyclic hydrazines

被引：31

作者：

Bertolini, Ferruccio ^{[1
]}

Macchia, Franco ^{[1
]}

Pineschi, Mauro ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim Bioorgan & Biofarm, I-56126 Pisa, Italy

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 52期

关键词：

D O I：

10.1016/j.tetlet.2006.10.153

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The development of a novel asymmetric ring opening of bi- and polycyclic hydrazines with aryl organometallic reagents is presented. The application of this reaction to the most simple bicyclic hydrazine la gives a straightforward regio- and diastereoselective access to synthetically useful trans 3,4-disubstituted hydrazinocyclopentenes in an enantioenriched form. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：9173 / 9176

页数：4

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