First example of a conducting polymer synthesised in supercritical fluids

被引：33

作者：

Kerton, FM ^{[1
]}

Lawless, GA ^{[1
]}

Armes, SP ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM PHYS & ENVIRONM SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 10期

关键词：

D O I：

10.1039/a704479h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polypyrrole is synthesised via thermal decarboxylation of a precursor monomer, pyrrole-2-carboxylic acid, using ferric salts in both supercritical carbon dioxide and supercritical fluoroform; pressed pellet conductivities were as high as 2 x 10(-2) S cm(-1) and scanning electron microscopy studies revealed an unusual non-spherical morphology.

引用

页码：1965 / 1966

页数：2

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