Diphilic carbosilane dendrimers with different densities of the hydrophilic layer

被引：10

作者：

Getmanova, EV ^{[1
]}

Tereshchenko, AS ^{[1
]}

Ignat'eva, GM ^{[1
]}

Tatarinova, EA ^{[1
]}

Myakushev, VD ^{[1
]}

Muzafarov, AM ^{[1
]}

机构：

[1] Russian Acad Sci, NS Enikolopov Inst Synthet Polymer Mat, Moscow 117393, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

hydrophilizing reagents; hydrosilylation; polyhydroxyl carbosilane dendrimers;

D O I：

10.1023/B:RUCB.0000024842.72905.c7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A universal method for the synthesis of hydrophilic dendrimers was considered. The method is based on a combination of carbosilane dendrimers with different molecular organizations and hydrophilizing agents, viz., substituted hydride silanes containing one and three protected hydroxyl groups. The combination of a limited set of the mentioned reagents makes it possible to control the ratio of hydrophilic and hydrophobic moieties of the molecular structure in wide limits. A simple and convenient method for the removal of trimethylsilyl protection of hydroxyl groups in the surface layer of dendrimers was developed.

引用

页码：137 / 143

页数：7

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