Toward effective chiral catalysts containing the N-P=O structural framework for the borane-mediated asymmetric reduction of prochiral ketones

被引：31

作者：

Basavaiah, D ^{[1
]}

Reddy, GJ ^{[1
]}

Rao, KV ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 12期

关键词：

D O I：

10.1016/j.tetasy.2004.05.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Representative chiral catalysts containing the N-P=O structural framework having (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo[3.3.0]octane moiety with amino groups of varying steric requirements on phosphorus, have been synthesized and their applications in the borane-mediated asymmetric reduction of prochiral ketones described. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1881 / 1888

页数：8

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