Toward a total synthesis of an aglycone of spiramycin; A chiron approach to the C-1/C-4 and the C-13/C-15 fragments

被引：14

作者：

Breuilles, P ^{[1
]}

Oddon, G ^{[1
]}

Uguen, D ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,ECOLE EUROPEENNE CHIM POLYMERES & MAT,CNRS,SYNTH ORGAN LAB,F-67008 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(97)01523-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acetalisation of p-anisaldehyde by either (R) or (S)-butanetriol has been shown to occur selectively and quantitatively by using Noyori's protocol. The crystalline dioxane derivatives R-6a and S-ba which formed respectively, in these conditions have been convened efficiently into the title fragments of spiramycin. (C) 1997 Elsevier Science Ltd.

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页码：6607 / 6610

页数：4

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