Rheological and electrical properties of polycarbonate/multi-walled carbon nanotube composites

被引:151
作者
Sung, Y. T.
Han, M. S.
Song, K. H.
Jung, J. W.
Lee, H. S.
Kum, C. K.
Joo, J.
Kim, W. N. [1 ]
机构
[1] Korea Univ, Dept Biol & Chem Engn, Seoul 136701, South Korea
[2] LG Chem Ltd, Ctr Tech, Taejon 305343, South Korea
[3] Korea Univ, Dept Phys, Seoul 136701, South Korea
关键词
multi-walled carbon danotube composite; rheological properties; electrical properties;
D O I
10.1016/j.polymer.2006.04.008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Rheological and electrical properties of the polycarbonate (PC)/multi-walled carbon nanotube (MWNT) were studied. The MWNT was funtoinalized by treating with the hydrogen peroxide (H2O2). The H2O2 treated MWNT was dried by thermal and freeze drying methods. From the morphological studies, the degree of entanglement of the MWNT was decreased after treating with the H2O2. For the H2O2 treated MWNT (thermal drying), the length of the MWNT was shortened compared that of the H2O2 treated MWNT (freeze drying). The rheological and electrical properties of the PC/MWNT (H2O2 treated) composites increased compared that of the PC/MWNT (untreated) composites. Also, the electrical conductivity showed higher value for the PC/MWNT (H2O2 treated, freeze drying) composites compared that of the PC/MWNT (H2O2 treated, thermal drying) composites. From the results of the morphological, rheological, and electrical properties of the PC/MWNT composites, it is suggested that the electrical and rheological properties of the PC/MWNT composites are affected by the MWNT-MWNT network structure, which is related with the MWNT morphologies such as the degree of aggregation and aspect ratio of the MWNT. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4434 / 4439
页数:6
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