Thioureas: new ligands for the metal catalyzed asymmetric reduction of carbonyl compounds

被引:50
作者
Touchard, F
Fache, F
Lemaire, M
机构
[1] UNIV LYON 1,CPE,INST RECH CATALYSE,F-69622 VILLEURBANNE,FRANCE
[2] UNIV LYON 1,CPE,CNRS,LAB CATALYSE & SYNTH ORGAN,F-69622 VILLEURBANNE,FRANCE
关键词
D O I
10.1016/S0957-4166(97)00396-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The catalytic enantioselective hydride transfer reduction of prochiral ketones using differently substituted mono and dithioureas with several catalyst precursors is reported. The best results are obtained with a ruthenium complex and a C-2 symmetric ligand. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3319 / 3326
页数:8
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